The biosynthesis of broussonetines: origin of the carbon skeleton.
نویسندگان
چکیده
Broussonetines are glycosidase-inhibitory alkaloids obtained from Broussonetia kazinoki. Feeding experiments using [1-13C]glucose and 13C-NMR spectroscopic studies showed that broussonetines are biosynthesized through routes similar to those of sphingosine and phytosphingosine.
منابع مشابه
Topological Relationship Between One-Dimensional Box Model and Randić Indices in Linear Simple Conjugated Polyenes
The alternative double bonds and conjugation in the polyene compounds are one of the main properties in these compounds. Each carbon-carbon bonds in a polyene compound along the chain has appreciable double-bond character. The p-electrons are therefore not localized but are relatively free to move throughout the entire carbon skeleton as an one-dimensional box. The skeleton be considered as a r...
متن کاملGreen Biosynthesis of Silver Functionalized Multi-Walled Carbon Nanotubes, Using Satureja Hortensis L Water Extract and Its Bactericidal Activity
Green biosynthesis of silver - functionalized multiwalled carbon nanotube (Ag/FMWCNT) nanohybride from silver nitrate solution using water extract of Satureja hortensis L as reducing agent and FMWCNT as anchoring agent at room condition was succesfully carried out. Water-soluble organics present in the plant materials were mainly responsible for the reduction of silver ions to nano-sized Ag par...
متن کاملEffect of Various Carboxylic Acids on the Biosynthesis of Polyhydroxyalkanoate in Pseudomonas aeruginosa PA01
In the present study, four carbon sources were tested for the polyester synthesis of Pseudomonas aeruginosa PA01 which is a ubiquitous environmental bacterium and is one of the top three causes of opportunistic human infections. These included linear C8 to C11 carboxylic acids. Octanoic acid, nonanoic acid, decanoic acid and undecanoic acid were added to M1 ...
متن کاملSaponins, classification and occurrence in the plant kingdom.
Saponins are a structurally diverse class of compounds occurring in many plant species, which are characterized by a skeleton derived of the 30-carbon precursor oxidosqualene to which glycosyl residues are attached. Traditionally, they are subdivided into triterpenoid and steroid glycosides, or into triterpenoid, spirostanol, and furostanol saponins. In this study, the structures of saponins ar...
متن کاملPhotocatalytic Reduction of CO2 to Formaldehyde: Role of Heterogeneous Photocatalytic Reactions in Origin of Life Hypothesis
Photocatalytic reduction of carbon dioxide to formaldehyde was investigated on four semiconductor photocatalysts (FeS, FeS/FeS2, NiO and TiO2). The reaction was carried out in continues flow of CO2 gas bubbled into the reactor. Semiconductor photocatalysts were characterized by X-Ray diffraction (XRD) and Diffuse Reflectance Spectroscopic (DRS) methods. Sulfide ion was used as hole scavenger. T...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
- Chemical & pharmaceutical bulletin
دوره 49 4 شماره
صفحات -
تاریخ انتشار 2001